Abstract
Re-Os geochronology of fractions composed of unsized, coarse, and fine molybdenite from a pod of unusual monazite-xenotime gneiss within a granulite facies paragneiss, Hudson Highlands, NY, yielded dates of 950.5 ± 2.5, 953.8 ± 2.6, and 941.2 ± 2.6. Ma, respectively. These dates are not recorded by co-existing zircon, monazite, or xenotime. SEM-BSE imagery of thin sections and separated grains reveals that most molybdenite grains are composed of core and rim plates that are approximately perpendicular. Rim material invaded cores, forming irregular contacts, probably reflecting dissolution/reprecipitation. EPMA and LA-ICP-MS analyses show that cores and rims have different trace element concentrations (for example, cores are relatively enriched in W). On the basis of inclusions of zircon with metamorphic overgrowths, we conclude that molybdenite cores and rims formed after high-grade regional metamorphism. The discovery of cores and rims in individual molybdenite grains is analogous to multi-component U-Pb geochronometers such as zircon, monazite, and titanite; thus, molybdenite should be carefully examined before dating to ensure that the requirement of age hom*ogeneity is fulfilled.
Original language | English |
---|---|
Pages (from-to) | 55-60 |
Number of pages | 6 |
Journal | Chemical Geology |
Volume | 300-301 |
DOIs | |
Publication status | Published - 18 Mar 2012 |
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Aleinikoff, J. N., Creaser, R. A., Lowers, H. A., Magee, C. W., & Grauch, R. I. (2012). Multiple age components in individual molybdenite grains. Chemical Geology, 300-301, 55-60. https://doi.org/10.1016/j.chemgeo.2012.01.011
Aleinikoff, John N. ; Creaser, Robert A. ; Lowers, Heather A. et al. / Multiple age components in individual molybdenite grains. In: Chemical Geology. 2012 ; Vol. 300-301. pp. 55-60.
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title = "Multiple age components in individual molybdenite grains",
abstract = "Re-Os geochronology of fractions composed of unsized, coarse, and fine molybdenite from a pod of unusual monazite-xenotime gneiss within a granulite facies paragneiss, Hudson Highlands, NY, yielded dates of 950.5 ± 2.5, 953.8 ± 2.6, and 941.2 ± 2.6. Ma, respectively. These dates are not recorded by co-existing zircon, monazite, or xenotime. SEM-BSE imagery of thin sections and separated grains reveals that most molybdenite grains are composed of core and rim plates that are approximately perpendicular. Rim material invaded cores, forming irregular contacts, probably reflecting dissolution/reprecipitation. EPMA and LA-ICP-MS analyses show that cores and rims have different trace element concentrations (for example, cores are relatively enriched in W). On the basis of inclusions of zircon with metamorphic overgrowths, we conclude that molybdenite cores and rims formed after high-grade regional metamorphism. The discovery of cores and rims in individual molybdenite grains is analogous to multi-component U-Pb geochronometers such as zircon, monazite, and titanite; thus, molybdenite should be carefully examined before dating to ensure that the requirement of age hom*ogeneity is fulfilled.",
keywords = "Geochemical analysis, Growth episodes, Molybdenite, Re-Os dating",
author = "Aleinikoff, {John N.} and Creaser, {Robert A.} and Lowers, {Heather A.} and Magee, {Charles W.} and Grauch, {Richard I.}",
year = "2012",
month = mar,
day = "18",
doi = "10.1016/j.chemgeo.2012.01.011",
language = "English",
volume = "300-301",
pages = "55--60",
journal = "Chemical Geology",
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}
Aleinikoff, JN, Creaser, RA, Lowers, HA, Magee, CW & Grauch, RI 2012, 'Multiple age components in individual molybdenite grains', Chemical Geology, vol. 300-301, pp. 55-60. https://doi.org/10.1016/j.chemgeo.2012.01.011
Multiple age components in individual molybdenite grains. / Aleinikoff, John N.; Creaser, Robert A.; Lowers, Heather A. et al.
In: Chemical Geology, Vol. 300-301, 18.03.2012, p. 55-60.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Multiple age components in individual molybdenite grains
AU - Aleinikoff, John N.
AU - Creaser, Robert A.
AU - Lowers, Heather A.
AU - Magee, Charles W.
AU - Grauch, Richard I.
PY - 2012/3/18
Y1 - 2012/3/18
N2 - Re-Os geochronology of fractions composed of unsized, coarse, and fine molybdenite from a pod of unusual monazite-xenotime gneiss within a granulite facies paragneiss, Hudson Highlands, NY, yielded dates of 950.5 ± 2.5, 953.8 ± 2.6, and 941.2 ± 2.6. Ma, respectively. These dates are not recorded by co-existing zircon, monazite, or xenotime. SEM-BSE imagery of thin sections and separated grains reveals that most molybdenite grains are composed of core and rim plates that are approximately perpendicular. Rim material invaded cores, forming irregular contacts, probably reflecting dissolution/reprecipitation. EPMA and LA-ICP-MS analyses show that cores and rims have different trace element concentrations (for example, cores are relatively enriched in W). On the basis of inclusions of zircon with metamorphic overgrowths, we conclude that molybdenite cores and rims formed after high-grade regional metamorphism. The discovery of cores and rims in individual molybdenite grains is analogous to multi-component U-Pb geochronometers such as zircon, monazite, and titanite; thus, molybdenite should be carefully examined before dating to ensure that the requirement of age hom*ogeneity is fulfilled.
AB - Re-Os geochronology of fractions composed of unsized, coarse, and fine molybdenite from a pod of unusual monazite-xenotime gneiss within a granulite facies paragneiss, Hudson Highlands, NY, yielded dates of 950.5 ± 2.5, 953.8 ± 2.6, and 941.2 ± 2.6. Ma, respectively. These dates are not recorded by co-existing zircon, monazite, or xenotime. SEM-BSE imagery of thin sections and separated grains reveals that most molybdenite grains are composed of core and rim plates that are approximately perpendicular. Rim material invaded cores, forming irregular contacts, probably reflecting dissolution/reprecipitation. EPMA and LA-ICP-MS analyses show that cores and rims have different trace element concentrations (for example, cores are relatively enriched in W). On the basis of inclusions of zircon with metamorphic overgrowths, we conclude that molybdenite cores and rims formed after high-grade regional metamorphism. The discovery of cores and rims in individual molybdenite grains is analogous to multi-component U-Pb geochronometers such as zircon, monazite, and titanite; thus, molybdenite should be carefully examined before dating to ensure that the requirement of age hom*ogeneity is fulfilled.
KW - Geochemical analysis
KW - Growth episodes
KW - Molybdenite
KW - Re-Os dating
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U2 - 10.1016/j.chemgeo.2012.01.011
DO - 10.1016/j.chemgeo.2012.01.011
M3 - Article
SN - 0009-2541
VL - 300-301
SP - 55
EP - 60
JO - Chemical Geology
JF - Chemical Geology
ER -
Aleinikoff JN, Creaser RA, Lowers HA, Magee CW, Grauch RI. Multiple age components in individual molybdenite grains. Chemical Geology. 2012 Mar 18;300-301:55-60. doi: 10.1016/j.chemgeo.2012.01.011